I think the default Ubuntu Humanity theme is nice but it just needs some tweaking. What I did was change the toolbar background and got the monoblin icon theme from "Picklesworth" on ubuntu art.
If only all the applications would play nice (and use the system theme, icons and work with appmenu) so we could enjoy a desktop that is just as visually pleasing as it is to work with

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...with your last statement! I hate anything that Apple makes! Apple sux even more than M$!